 After pipetting volatile liquids (like β-mercaptoethano), some of the liquid will vaporise when it is in your pipette tip. This could enter the pipette itself when you release the pipette's dispensing button. So try to use a filter tip to stop this from happening. Otherwise, make sure you eject the tip from the pipette right after dispensing the liquid from it - don't release the button from the "second stop" or it could suck up the vaporised liquid into the pipette itself.
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